Why it's interesting: Understanding and predicting energy transfer trends in low-dimensional heterostructures is essential to engineer devices with advantageous energy conversion and transport properties.
What we achieved: In collaboration with the experimental work of Archana Raja, Louis Brus, Tony Heinz and coworkers, we employed classical electromagnetic theory to show that contrasting trends of nonradiative energy transfer from quantum dots to two-dimensional (2D) stacks of graphene and MoS2 of different thicknesses (see figure) arise from the competition between screening and absorption of the electric field of the quantum dot dipole inside the 2D materials. We also employed our analysis to predict NRET behavior for the near-field coupling of a chromophore to a range of semiconducting and metallic thin film materials.
Relevant paper: Raja, AMC*, Zultak*, Zhang, Ye, Roquelet, Chenet, van der Zande, Huang, Jockusch, Hone, Reichman, Brus, & Heinz. Nano Lett. 16, 2328. (2016)